Controlled reaction systems

ABSTRACT

IN THE PARTICULAR EMBODIMENTS OF THE INVENTION DESCRIBED HEREIN, GAS-LIQUID REACTIONS ARE CARRIED OUT BY CONTINUOUSLY INJECTING THE NORMALLY GASEOUS REACTANT INTO A CONFINED STREAM OF THE LIQUID REACTANT AND PASSING THE GAS-LIQUID MIXTURE THROUGH A CONFINED TORTUOUS FLOW PATH SO AS TO INDUCE TURBULENCE IN THE MIXTURE. TYPICAL REACTIONS ARE AMMONIA-PHOSPHORIC ACID REACTIONS AND CHLORINATION AND HYDROGENATION REACTIONS.

3 Sheets-Sheet 1 Filed May 28, 1971 22 TO DIRECT CONDENSER AND VACUUM JETS PRODUCT A COOLER HEATING FLUID OUTLET INVENTOR.

PAUL s. MINOR ZONE HEATING:

FLUID INLET u I I I I I I I Illllltll R u I J P M v 23.5

AMMONIA United States Patent 3,809,708 CONTROLLED REACTION SYSTEMS Paul S. Minor, Fort Lauderdale, Fla., assignor to Parkson Corporation, Fort Lauderdale, Fla. Continuation-impart of application Ser. No. 9,590, Feb. 9,

"1970. This application May 28, 1971, Ser. No. 148,096 Int. Cl. C05b 11/04; Cllc 3/12 US. Cl. 260-409 11 Claims ABSTRACT OF THE DISCLOSURE In the particular embodiments of the invention described herein, gas-liquid reactions are carried out by continuously injecting the normally gaseous reactant into a confined stream of the liquid reactant and passing the gas-liquid mixture through a confined tortuous flow path so as to induce turbulence in the mixture. Typical reactions are ammonia-phosphoric acid reactions and chlorination and hydrogenation reactions.

CROSS REFERENCES TO RELATED APPLICATIONS This application is a continuation-in-part of application Ser. No. 9,590, filed Feb. 9, 1970.

BACKGROUND OF THE INVENTION This invention relates to a process for carrying out chemical reaction between gaseous and liquid reactants wherein rapid and intimate mixing of the reactants is required. In the past it has been common practice to carry out gas-liquid reactions in a reaction vessel and to allow the entire batch to react prior to removal of the product. With that process, however, mechanical agitation is usually necessary and hold-up times can be quite long (e.g. an hour or more). The long hold-up times necessary for adequate gas-liquid reaction not only adversely affect the efficiency of the process, but also result in poor selectivity of the product. Thus, the desired product may continue to be exposed to reaction conditions and be further transformed into undesirable products. It is also possible that the conditions within the reaction vessel may become such that the reaction reverses and the desired final product reverts to some intermediate product. Furthermore, even with the long hold-up times, it is frequently impossible in the batch-type method to maintain contact between the reactants for a sufficient time to assure complete reaction.

These ditficulties are not avoided by the various continuous reaction methods wherein the reactants are continuously supplied to a reaction vessel and the reaction more prevalent in liquid-liquid reactions and throughput was felt to be severely limited. Since many gas-liquid reactions are controlled by mass transfer of gas into the liquid phase, and since this rate of transfer under prior art conditions was relatively low, it was erroneously concluded that such apparatus could not be made suitable for gas-liquid reactions and no efieort was made to make such systems. It has now been found, however, that the great reduction in the mass transfer resistance made possible by a properly designed fiow path brings on a several fold increase in the overall reaction rate, thus making it possible to carry out a great number of industrially important reactions in this apparatus.

SUMMARY OF THE INVENTION In accordance with the present invention, a gas-liquid reaction process is provided wherein a gas reactant and a. liquid reactant are intermixed and passed continuously through a tortuous flow path so as to induce high turbulence in the mixture and thereby maintain intimate contact between the reactants throughout the reaction period, the temperature and pressure conditions within the flow path being controlled so as to assure substantially complete reaction of the constituents. According to one embodiment of the invention, vegetable oils are hydrogenated by introducing hydrogen into a flowing turbulent stream of the liquid oil within a tortuous flow path to form semi-solids suitable for use in shortening or margarine. In another embodiment, ethylene is chlorinated to form ethylene dichloride. Still another embodiment involves the ammoniation of phosphoric acid to form ammonium phosphate and related products.

BRIEF DESCRIPTION OF THE DRAWINGS [For a more detailed explanation of the invention, reference may be made to the following description of exemplary embodiments taken in conjunction with the figures of the accompanying drawings, in which:

FIG. 1 is a schematic diagram illustrating a representative' system including a tortuous path. plate reactor for carrying'out reactions according to the invention;

FIG. 2 is a schematic sectional view showing one form of the plate reactor used in the system of FIG. 1 for the ammoniation and concentrationof phosphoric acid;

FIG. 3 is a schematic sectional view showing a form of 1 the plate reactor used in the system of FIG. 1 for the product is continuously removed. Even in the plug-flow 4 type of continuous reactor, which consists essentially of a simple tube through which the reactants pass, the close temperature and pressure controls and continuous agitation required for many reactions involving gaseous reactants cannot be maintained. In the ammoniation of phosphoric acid to produce ammonium-polyphosphates, for example, the reaction temperature and pressure must be controlled carefully to assure complete reaction while avoiding reversionof the desired polyphosphate product. This cannot readily be accomplished in continuous flow pipes of the type disclosed in the patents to Coon et al. No. 3,125,420, LutzNo. 3,310,371, Kearns No. 3,464,808, Fitch No. 3,420,624 and Hudson No. 3,502,441, since the constituents are not agitated continuously during the reaction and precise temperature and pressure control are not possible in those reactors.

It has been proposed heretofore to carry out liquidliquid reactions in a plate type heat exchanger, but such apparatus presented, many practical difficulties and shortcomings as a reaction vessel. For example, backmixing vis ammoniation and concentration of phosphoric acid and the subsequent addition of water to obtain a fertilizer solution;

FIG. 4 is a schematic sectional view illustrating a form of the plate,reactor used in the system of FIG. 1 for ammoniation of phosphoric acid and the further treatment of the product to obtain various fertilizer materials;

FIG. 5 is a schematic sectional view showing a form of the plate reactor used in the system of FIG. 1 for the chlorination of ethylene to obtain ethylene dichloride;

,FIG, 6 is a schematic sectional view showing a form of the plate reactor used in the system of FIG. 1 for hydrogenation of vegetable oil to obtain semi-solids for use in the manufacture of shortening or margarine.

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention is especially useful in carrying out gas-liquid reactions which require close temperature and pressure control, or a short residence time, or which produce-a concentrated or dried molten product, but the advantages of the present invention may also be obtained with many other types of processes. Specific reactions in which the process is useful are ammoniation of hydrocarbonsto amines, ammoniation of nitricacid tion-ofboth' organic and inorganic components, sulfona-"---- tion and sulfation reactions, hydrogenation of edible oils, nitration of hydrocarbons with nitrogen dioxide and ammoniation of phosphoric acid to ammonium polyphos phates. In certain forms of the process, the normally gaseous reactant or reactants are continuously injected into a confined stream of the normally liquid reactant or reactants; In other reactions, a normally gaseous reactant may be introduced into the confined stream in itsliquid form or in solution, rather than in gaseous. form. It is also possible in some cases to inject the liquid into the gas to obtain :the desired results. The reactant mixture passesthrough a confined tortuous flow path such as a plate-type heat exchanger which has a high surface-tovolume ratio and which induces a high degree of turbulence. The high surface-to-volume ratios contemplated may be expressed by the'formula S/ V wherein S is the surface area-of the confining flow path in square feet per foot of length and V is the volume in cubic feet contained within this surface area. S/ V ratios of at least 50' are necessary in order-to obtain the requisite potential for adding heat to or removing heat from the flow'path through the flow path surfaces. 8/ V ratios .of at least 75 are preferred since the reactions contemplated may behighly exothermic and at the same time require close temperature controLto ensure ,product selectivity and prevent reversion of the reaction.

It has been found surprisingly that such a flow path otters an ideal gas-liquid reaction environment in that: (1) the high turbulence ensures that all of the. gas is contacted with the liquid in a very short time inthat the liquid particles have a high surface-to-volurne ratio and excellent surface renewal rates, (2) the residence time may be adjusted to allow the reaction to be satisfactorily completed, (3) the high 8/ V ratio together with high turbulence permits close temperature control by the use of heating or cooling fluids, (4) the configuration of the flow path may be arranged so as to cause a controlled pressure letdown thereby allowing for the releasepf vapors in a controlled manner, and (5) the turbulent flow and high 8/ V ratio permit the efifectiv ej" utilization of catalytically activated flow path surfaces. (This feature serves to eliminate the necessity of premixing a catalyst powder with the feed material and subsequently filter ing the powder from the product.) f Z v w In certain instances, it may be desirable to g ppy an excess of the gaseous constituent to assure substantially complete reaction of the liquid constitut'ent. In such cases the excess gaseous constituent may be separated from the reaction product and recycled through the process.

Because it is easily adjusted to satisfy any or all of the foregoing requirements, a preferred tortuous flow path is made up of successive passes between the plates of the platetype heat exchanger, and, by inserting or removing plates and by'suitably arranging the connecting portals, a flow path having 'thedesired characteristics may be obtained. Also, because the plates are preferably quite thin to allow for optimum heat'transfer char acteristics, exotic alloys having certain desired-properties (e.g. corrosion resistance, etc.) can-be employed without prohibitive capital outlays. An added advantage of the plate type heat exchanger is'that it is quite 'eas to obtain high S/V ratios. l A typical reaction for which the novel process of the present invention is particularly suited is the ammoniation of phosphoric acid to produce ammonium polya feed line 11 into a plate reactor 12 comprising a series of thin'metal plates disposed in spaced parallel relation with appropriate gaskets so as to provide a series of narrow material flow passages arranged in the manner described in connection with FIGS. 2, 3, and 4. Where it is desirable to heat or cool the flow path, alternate parallel passes in the reactor may be supplied with a heating or cooling fluid to allow for easy temperature control of the flow path. The plate reactor 12, which may be of the same general type and structure as the plate packdescribed in the US. Pat. No. 3,073,380 to 'Einar H. Palmason, induces a high degree of turbulence to the stream of phosphoric acid continuously throughout its passage through the reactor. While that Palmason patent describes the general type of plate pack useful 'in the present invention, certain significant changes in the plate arrangement such as providing a substantially greater S/V ratio, are necessay to render the ap-' paratus suitable for the purposes of the present inven? tion'.

The reactor arrangement schematically depicted" in FIG. 2 is a'suitable configuration for the ammoniation and concentration of phosphoric acid having a P 0 content of from about 32% to about 72% and preferably from 54% to 64%. The phosphoric acid is introduced into the'plate reactor through line 11 and enters a confined flow path which is comprised of the adjacent parallel passes 13 between the thin gasketed plates 14 of the reactor.

When ammoniating phosphoric acid having a low to moderate P 0 concentration such as 32% to 60%, it is preferable to preheat the phosphoric acid in a preheat zone 15 to a temperature not exceeding about 500 F. prior to the injection of ammonia. Preheating is not necessary if a fairly concentrated feed material (greater than 60% P 0 is used or if a low level of polyphosphates' (less than 10%) is required. In FIG. 2 steam is supplied from a heating fluid input through three alternate passes 16 so that the walls of the two intervening passes 13 of the flow path are heated;

If desired, the feed acid may be preammoniated without appreciable solids formation to a pH between about 1.3 and 2.5 to reduce its corrosiveness. This preammoniation can be carried out advantageously by scrubbing the effluent ammonia gases from the reactor output with the .feed acid to be applied to the line 11 to recover any unreacted ammonia. a

In the reactor shownin FIG. 2, two preheat passes of the preheat zone. 15 are designated as being in a 1-1 configuration ,for purposes of description,-there being one upwardly directed pass followed by one downwardly directed pass. It will be apparent, however, that the plate configuration may be altered depending upon the conditions required forlthe process. For example, a reaction zonel'] following. the preheat zone of FIG. 2 has a 1+1-2 configuration, there being one upwardly directed pass followed by one downwardly directed pass and thence two upwardly directed passes.

' fter' preheating in the, zone 15, the phosphoric acid stream passes ou't of the preheat zone and into thereaction zone .17. At a point 18 located between the preheat zone and the reaction zone, ammonia is injected into the fiowing stream of phosphoric acid. This injection is accomplished most conveniently by using a properly designed and constructed injection plate, having one or more passageways communicating with the outside of the package through which gaseous, liquid, or aqueous ammonia can be' metered, that plate being inserted at the proper location with the plate package. If desired, several injection plateszmay be included in theplate reaction to permit introduction of constitutents at various locations in the-reactionzone. For applications of the type described hereinyno special mixing'valve or nozzle need be employed' in' the injection plate since, as will be more fully discussed below, the highly tortuous character of the flow path induces immediate and continuous mixing of the t t q i m: J I." 1.11

-Depending upon the desired composition of the' pr'oduct and the P concentration of the feed acid, the molar ratio of the injected ammonia to P 0 may varybet-ween about .4 to 1 and about-5.8 to 1 and, for-normal operation, is preferably about 3.0 to'l. The ammonia-acid mixture passes immediately into the-reactionzo'ne 17 where the ammonia reacts vigorously on contact with the phosphoric acid. As mentioned above, the-reaction zone is comprised of the narrow pa'rallel'passes between the thin gasketed plates. The tortuousness of the flow path within the reaction zone causes extreme turbulenece and ensures that all the ammonia is contacted with the phosphoric acid in a very short time. The number of plate passes in the reaction zone is selected so as to assure a flow path of suflicient length to 'allow'for substantial completion of the reaction. i

The ammonia reacts exothermally' with the phosphoric acid, and in the embodiment of FIG. 2 the temperature within the flow path rises above the vaporization point of water at the prevailing pressures so that water vapor is evolved, the plate configuration being selected so that the proper pressure within the flow path is obtained.- This causes the ammonium phosphate to be concentrated to the point where polyphosphates are formed and the desired degree of concentration of the phosphate product can be achieved readily. The 1l-2 configuration illustrated in FIG. 2 is designed to allow for a gradual pressure drop which, when combined with the temperature increase, facilitates the vapor formation. Generally speaking, temperatures between about 350 F. and about 650 F. are required for polymerization whereas a temperature range of 400 F. and 600 F.'is preferred; If a product containing more than 50% polyphosphates is desired, temperatures of at least about 550 F. are'necess'ary.

The evolution of the water vapor in the reaction zone 17 causes an increase in the volume of material within the confined flow path and the. material is thus rapidly accelerated toward the outlet 19 of'the reactor. A high velocity stream containing a 'mixture of water vapor, molten ammonium polyphosphate,*and any unreacted ammonia emerges from the reactor. As illustrated in FIG.

1, this stream is directed to a conventional cyclonic separator 20. The molten ammonium polyphosphate collects at the bottom of the separator and flows out of the system through a' line 21 through which it may pass to a granulator (not shown) following cooling, if desired. The water vapor and any unreacted ammonia .are drawn off the top of the separator through a line 2 2 which leads to a condenser and a vacuum line (not shown). As mentioned above, the gaseous effluentmay be scrubbed with the feed acid to extract unreacted ammonia.

Using the process described above various gradesof ammonium phosphate product, can be made, depend ng upon the ratio of ammonia to P 0 and' the concentration increase desired. In addition, certain..changes, may be made in the plate package so asto alter' the reaction product. For example, as is depicted in FIG. 3, additional plates may be included in theplate package beyond the reaction zone 17 so as to permit the injection of water to quench the reaction product and produce an immediately usable 'base fertilizer solution, such as -34-0. In this case, another injection plate 23is intwo cooling passes 25 through which a coolant is circu ing different compositions may be produced in a similar fertilizer solutions hav- 6 manner by merely adjusting the concentrations and proportions of the reactants and by varying the conditions within the reactor. V

The embodiments described above relate to the ammoniation of phosphoric acid solutions having only moderate P 0 concentrations. It is also possible, however, to utilize the process according to the invention for the ammoniation of preconcentrated superphosphoric acid having much higher P 0 concentrations. To accomplish this, a plate reactor such as is shown in FIG. 4 is employed having no preheat zone. Instead, the first plate in the package is an injection plate 29 through which ammonia is injected into the stream of superphosphoric acid introduced at an inlet port 30. The absence of the preheat zone also makes it possible to inject the ammonia directly into the inlet port if desired. Preferably, the rate at which ammonia is injected is controlled in accordance with the phosphoric acid flow rate so as to obtain a product of optimum pH, normally about 6.0 to 7.0.

When ammoniating superphosphoric acid in this Way, it is-necessary to cool the material in the passes 31 comprising reaction zone by providing cooling fluid to the alternate passes 32. This cooling removes excess heat resulting from the ammonia-superphosphoric acid reaction and thereby prevents the ammonium polyphosphate from reverting to the orthophosphate form. The high surface-to volume ratio of the exchanger and the excellent heat conductivity of the thin plates make it possible to maintain the temperature at the end of the reaction zone well below the temperature of about 250 F. at which such reversion becomes significant. Generally speaking, it is preferred that the temperature at the end of the reaction zone is about F. or below.

Although the reaction product is useful by itself, it is often desirable to manufacture a complete composite fertilizer containing other constituents in the same plate package. For this purpose, additional materials, such as water, clay, potassium solutions, micronutrients, and the like, are introduced through a second injection plate 33 in'the cooling zone. The composite fertilizer product then passes through a cooling pass 34 and thence out of the reactor.In this way, a complete suspension or solution fertilizerproduct (e.g., such as 15-15-15 or 7-21-21) can be manufactured from the basic raw materials in one apparatus. r

In another embodiment of the invention ethylene is chlorinated to form 1,2 dichloroethane (ethylene dichloride). This'chlorination reaction requires precise temperature control since the reaction is highly exothermic and overchlorination (yielding products other than ethylene dichloride) may occur at localized high temperature areas. Also, it is important to maintain the reactants in a uniformly mixed condition as they pass through the reactor since either backmixing or the uneven distribution of the reactants at particular points within the flow path can upset the stoichiometry of the reaction and likewise adversely afiect product selectivity.

"By employing the process according to the invention, the above requirements can be met. Because the reaction between gaseous ethylene and gaseous chlorine is highly exothermic, indeed explosive, it is preferable to dissolve either the ethylene or the chlorine in liquid ethylene dichloride prior to reacting the ethylene with the chlorine. The ethylenedichloride can be obtained by recycling a portion of the reaction product. Referring to FIG. 5, liquid ethylene dichloride having ferric chloride catalyst dissolved therein is passed through a feed line 35. Gaseous ethylene, for example, is then injected into the ethylene dichloride by an injector 36 just prior to entering the plate reactor through an inlet portal 37. In order to dissolve a portion of the injected ethylene in the ethylene dichloride, the ethylene-ethylene dichloride is first passed through a mixing zone 38 comprising upwardly directed parallel passes 39 and downwardly directed passes 40. The turbulent flow conditions within the mixing zone cause the dissolved ethylene-ethylene dichloride solution to approach very quickly the limit of solubility under the existing temperature and pressure conditions.

Gaseous chlorine is then injected into the ethylene-ethylene dichloride solution by means of an injection plate 41 and the reaction gas-liquid mixture is immediately passed into a reaction zone 42. It will be appreciated that more than one injection plate may be employed so as to more closely control the concentrations of the various reactants at given points within the reaction zone. The reaction zone comprises several alternate parallel passes 43 of the plate reactor so as to provide ahigh degree of tur bulence in the reacting mixture. This turbulence assures that the chlorine will be intimately'mixed with the ethyl: ene-ethylene dichloride solution and the ferric chloride catalyst and thus be completely reacted with the ethylene. In order to maintain close temperature control and thus assure high product selectivity, several adjacent parallel passes 44 are provided through which a-cooling, fluid, preferably water, is passed; Because of the high surfaceto-volume ratio within the flow path, the coolingfluid is capable of preventing localized overheating within thefiow path and over chlorination resulting in undesirable products is avoided. v

Upon emerging from the reaction zone the mixture of gas (now greatly depleted) and liquid is passed into a separatorwhere any remaining gaseous material, such as any inert gas introduced with the feed material, unreacted ethylene, unreacted chlorine, or product gases, are separated from the liquid product. a

It Will be appreciated that, by suitably balancing the ratio of reactants, either the ethlylene or the chlorine can be virtually completely reacted by an excess of the other reactant. Also, by providing a reaction zone of sufiicient length, the reaction can be carried substantially to completion so that any unreacted gases represent no -signi-fi-' cant recycle cost or economic loss. 7 I

The production of chlorinated products other than 1,2- dichloroethane is also possible by modifying the reactants, the stoichiometry of the reactants, the catalyst and..cata-v lyst concentration, and the reaction temperature. Some of the other reactions contemplated are the chlorination oji ethylene dichloride to further chlorinated products; such as trichloroethane, tetrachloroethane, pentachlpr oethane, and hexachloroethane; chlorination of benzene tomorrochloro, dichloro andhigher chlorinated derivatives; chlorination of other cyclic carbon compounds such asdicyclo-v pentadiene; chlorination ofmethane or partially chlorinated single carbon molecules to methyl cr -methylene chloride or to chloroform. or carbon tetrachloride; chlorination of other aliphatic hydrocarbons; and chlorination of polymeric materials. In many cases, hydrogen chloride-is produced as a by-product of the chlorination ,rea ction Ir-i such cases, the evolution of the gaseous byproduct en hances the turbulence within the fiowv path and aids-and maintains highfiow velocities. It may also be preferred to heat a portion of the flow path so as to heat a reactantor the reactant mixture and thus facilitate -the initiation,- of the chlorination reaction. f I:

In another preferred embodiment of the, invention, edible oils such as vegetable oil are hydrogenated to form semi-solid fats suitable for use in the manufacture of shortening or margarine. Other fats andQfatty-acids can, likewise, be hydrogenated to obtain useful products. This hydrogenation of oils, fats, fatty acidsorderivatives thereof according to the invention offers unique .adva ntages in that the turbulent flow characteristics of {the flow path enhance the dissolution of the hydrogen injthe oil. It is generally believed that the hydrogenation" reaction occurs after the hydrogen is dissolved in theoil'in presence of a catalyst. Furthermore, the close temperature control made possible by the invention com inedwith 'th surprising absence of backmixing of the r ctants" sulting in substantial plug flow) yields a high degree of product selectivity.

- Referringto FIGX6, a liquid oil having a'suitable catalyst mixed therewith is passed through a feed line 45 to the plate-typereactor, As the oil enters the reactor, gaseous hydrogen is injected into the oil through an in jector 46.-,This--mixture of hydrogen, edible oil, and catalyst then .pases through a preheating pass 47 in which the propertemperature for the initiation of the reaction is reached. Heat. is supplied to the heating pass 47 through a series of parallel plates 48 forming several alternate passes 49 through which a heating fluid such as oil olf steam is .circulated. As the reaction is carried out, the mixture passes through a reaction zone 50 comprising a series of parallel passes 51. The temperature in these passes is closely controlledv by a series of alternate cooling passes- 52 through which a cooling fluid such' as water is passed. Also injection points can be provided along the flow path for the addition of hydrogen or liquid reactant thus allowing further control of reaction selectivity .or productproperties through proper control of reactant concentration. The final mixture of hydrogenated oil and the catalyst: and anyunreacted hydrogen is thenpassed to a .separator where any unreacted. hydrogen is removed for recycle or other use and the product is drawnoff in liquid form,.filtered to remove the catalyst, and cooled to solidify the product. a V V ,Normallysubstantially-all of the hydrogen will react with the oil an d very little, if any, will be obtained from the, separation. This result, which is quite surprising and unexpected in view of the very short residence time in the reactor, can be attributed to the high turbulence imparted by the, tortuous flow path combinedwith the plug flow characteristic which isnotordinarily obtainable in other typesof continuous reaction processes.

An important, modification of the above-described hydrogenation reaction, available only with the process of the Present, ention'utilizes flow path surfaces which are cataly'tically ctivated (either by activation of the surface itselfonzby coating the surface with a catalyst). With this .process it is;possible to=. carry out hydrogenatiorireaction; withoutpremixing theicatalyst with theo'il or filter= ingitfro n the finalproduct. 1

.Iarticular examples ofconstituents conditions and results forsvario'us' zreactions carried out inaccordance with the presenlt invention are as: follows:

l r I 'EXA LE 1;: acid containing 2.7% solids rea an em nt:

' Tli'e final prodiict a' darlir colored solid analyzing 1% and 57,1 P 0 with 19% of the P 0 in nonortho" J if. ...V.i... .'ITemperature in line between, pack Concentration; ammoniationtand Hdilution..ofl 54%PO r. .aand separator V r. wet process phosphoric acid containing 2.7% solids to, provideafertilizer solution P I Plate arrangement: 75 l 9 Preheat Cooling HO out 124'F. Reactlon p 1-12. i L '1 1 l ---C0oling..a., --e 222. ---The product analyzed l0% N and 34%P O No solids S/ V ratio (ft. /ft. 10- precipitated after two months storage. The polyphosphate Preheat surface 5-2 ftp reversiontwas below 3%. NH injection '...L Atendofpreheat v H2O injection At end'bfreactron." EXAMPLES Reaction ath len th '6 feet r a. p a 1 d g "riff-f "*U: I Ammoniation and. dilution vof superphosphoric acid and 5 "t N 1 5 A addition oftother materialsto provide a composite -fer- 3 5': .i tilizerproduct I j H O t 110lbs./hr. I a I w v 1 54% P O "acid '27 9lbs./hr I I Temperature feed? I skfV r-atibtftfi/ft 210. H '7'"""',' 5 Cooling, reaction, blending path 7'*"'""""' 1 length 6 feet. Llqllld temperature out of pack g 119 v u wh, it w Pressure e i re -.-.---f F i W- -mNH '47:lbs./hr.'1-; PH qi Product? z Urea-ammonium nitrate solu- 7 Femhze? Pwdu ---\-.,--..v l -(Pia a tion(32-O0) 237 lbs./hr. Y Y r H 0* 72 lbs./hr.-

EXAMPLE 3 E 75%. P 0 acid 150 lbs/hr.

r a ;;r f Attapulgite clay (suspended in Ammoniation and dilution of furnace grade s'up rph e H O feed) 8 lbs/hr.

phoric acid analyzing 75% P 0 to give a fertilizer solu- Temperature of product out of tion containing ammonia and polyphosphates pack 4. 95 F.

' Product rate 514 lbs/hr.

v r .l "11 1 Cooling H O in 75 F. Plate configuration 111 .reactionwi hii; 99 5& 123

i 4 v l We?! ,939 i The resulting product, containing 22% N and 22% and K i? 9 3 1 it) P o can bf'e mixed with KCl and water to give a 15-15-15 "210. a l Reaction path length j 6 ffeet. gps'psglgqigrgl-l*zfr'- Feed rate: EXAMPLE 6 'NH 42s 'lbs'L/hr V V VHZO d 102 lbs F; nrca grade ethylene was chlorinated in a tortuous 75% P205 r 137-155.," flo path plat eype reactor arranged In accordance with Fed pressure 8 p.s.i.g.' liI G.,5.-,having an .S V ratio of 298 ftF/ftfi. The fo1low- Temperature in line between W 'f v? p v atbf 5- 02H; feed a 1m /hr 6.0 Temperature of Product 0 ,1 Chlorine feed 'L 1bs./hr 21 separator EDC recycle s/hr... 280 Pro r te *Feed re's'siire nsi 17 P -,----1 v -7; Reac'tiorflthiperature F 190 P B20111. 76 Cooling water temperature; F..- 83 Coollng zopii -y -e-r-r'" Product rate lbs./hr 26 1, nclfivrdqucja lb./hr.... 1 The product analyzed 9.4 N and 38.6% P 0 is ofpr'oduct by gas chromatograph:

t v tchlorinated products wt. percent A g r 1 {W Ethylene'fdichlor'ide do 89.0 EXAMPLE 4 I 6b f 1,]; trichloroe thane do 9.93 Ammoniation of furnace grade' superphosphoricacid aiiaf j 1-1 i-fehl'orinated products 'd0 12 lyzing 75% P 0 withthe pH of the product: Carefully bfEDC-C H i h i l- 41 controlled at 6.2 p Length.of, reactionpath do 41 Plate configurationsign-L"; 1'1 1--kreao'tioii path a v I EXA a with a and 'veral' 'were made in order to demonstrate the L 11 A injection, and utility of the, invention in conjunction with hydrogenaater cooling l jtidnof' eg able oil, using Harshaw'Nysel catalyst (25% S/ V ratio (ft. /ft. 210- 5 "'70 Nilrmxed'with the oil. The results of these test runs are Reaction path length 6 feet. as follows: Feed rate:

NH 39 lbs/hr. Plate configuration: 1-1-1v-1-11-1-1-1 H O 127 lbs./hr. S/ V ratio (ftF/ftfi): 298

75% P 0 acid -Q 137 lbs/hr. 75 Flow path length: 126" -='ful temperature and pressure control fined stream 6f the liquid reactan Run number 10 ll 1 Reaction temp, F. 5" .500 501 550 552 Reaction press, .s.i. 35. 0 a0 35. 0" I as. 0 Residence time, sec- 5.2 6.4 5.0 8.2 Velocity, ft.lsec.h. 5. 8 4. 7 6.0 3. 7 iiiiffiii 0.25 0.53 0. 5s 0. 55 0.20 I o. 25 0.14 n 12%.: 1 2' 122' g 1% 11% g g 1 Iodine value feed 1 .5 l (in 1; 104.0 "196.0 100.0 108 0 74.7 112.5 106.7 Iodine Va He pm 0 0.1 0.1 "0.1 0.1 0.1 0.1

Qatalyst cone. wt. p

The difference in the iodine values fdfith'e eed-"materlal and the product illustrates the extent of the hydrogenation resulting from the process.""

.1. 'In'iorder" :to sh'owi-jthe'product iselebtivity of Ethezhydm gen'atio'n reactions according w: zthe' invention, iithevlproducts from runs 3, 6, 8, and 11 were analyzed 'as follows. It should be noted that the product obtained in run ll approxir riates' that of acommercial margarine'zl husmhe relative amount of oleic acid (C18:l) has been maximized with relatir'iely littleformation of st 18:0)

M.P., F I 77.0 1" LV 103 2 0.0 Fatty acid compositions by gas chromatography: C-12 0.3 0.2

48.6 44.2 30.7 34.2 Trace Trace a. 4.0 0. 7 0.5 0.6,

It willbe apparent that the reaction conditions can be controlled to obtain either s'el yel'orfn y- 'clro'genation." Furthermore, iiianyp'ther gas iiq 'may be carried out iri'accordanife with the neon; foregoing examples being merely-illustrat advantag'eous'l results, not generally. ayai processes, are obtained when the re 'm sp c s uents somslste util z ti reactants, o limit 1 exposure of th more of thereactant materials I I claim:

1. A process for reacting} gas with a liquid. g rnpris ing continuously infermixing at least one norma If actant with atleast one liquid reactant, p s ng t .ture through a 'tortuo'u'sfiow' path'l'cofr'npri's'i parallel passes Within a plate-type react' (S/V ratio'of at least 500st; as 'tq' ssnr l'turbulence in the mixture," controllingthe Ite pressure within the flow pathso' asltoja'ch'e conversion of reactants,"and removingthe reaction prodnot from the tortuous flow path.

.Q n inu u l i je t n he sqq sr 3. Aproce'ss according to claim 11 of injectingan excessof the gaseous' r' passing the to mixing it .with the ot of eiisfftsfand their"derivatives' a roduct, and'rec'ycli'ng the exc'e 4. A process accor'dirig to claiml includingthe step of s. A 3 0 ess according to" claim 1' inclnding the' step of passes within aprate-rype reactor."

6. A process according to claim 1 ihcluding'the step or dissolving the-normally gaseous reactantina liquid [prior "reactant; 7 V f '1' p V. 0' claim 1 ff'or t he hydrogenation v H mixtures thereof including the steps of in'ter'mixing'gaseous hydrogen with a stream or the liquid reactant, passing the resultant mix ture through a tortuous flow path so as to induce or main- 7 A process accordi tain turbulence in the"rnixture, vcontrolling the tempera- :65 2. A process according to elaim 1 including the step tortuous fiow-ppath. i

ture and pressure within the flow path so as to initiate the reaction and'produce hydrogenated products, and removing: the. reaction product and any unreacted .H from the 8. A process according claim 7 inc luding the steps of passing the oil and hydrogen mixture through a heated flow path s9 as to heat the mixture andinitiate the rea c-.

fterf passing the reacting'mixtiirethrough d tortu us new path so as to remove a portion of the e'totherniicheat'of reaction from the reacting mixture.

9. A process according't'o'claim 7 -ir cliid'rigthe step of intermixing the liquid reactant and a suitable catalyst prior to the intermix ing of the gaseous hydrogen with'the liquid reactanty j I 10. A pro'ci 'e s a co ing to claim 7 whereinthe surfaces of the tortuous flow agthar'e' catalyticallyac'tive'and in.- cluding the steps ofbassing the; liquid reactant'and' hydrogen mixture through the "fl'ow path a nd causing the mixture to impinge upon .thejactivatd new" path surfaces to obtain the desired reaction. i i f 11. A proces'sj 'aceording to"claim"lwhereinfthe surfaces of the tbrtfid 1' How path are'catalytically activated and including the step's of passing the 'gas l iqu id mixture through a flow pat andfausing'the mixture to impinge upon the catalytidallyactiyefiow' path surfaces to' obtain the desired reaction Cited References UNITED PATENTS EhBER-T" ROBERTS, Primary Examiner c'tion, separating the unreacjt'led excess,

gaseg s liquid mixture throughsuccessi've' parallel.

PO-IOSO fummn STATES-PATENT OFFICE h 5 I F C TE OF CORRECTIO Patent. No. 3,809,708 i. Dated May 7' 1974.

Inuentofls) Mi I It is certified that error appears in the above-identified patent and shat said Letters Patent are hereby corrected as shown below:

r-hm Column 1, line 29, "reaction" should be n-reactions--. Column 4, line 70, 7 "reaction" should be -reactor-. Column 5', line '13, ".turbulenece" should be '-turbulence--. Column 8, line 6, "pases" should be -passes-. Column 9, 'line 38, "NH" should be -NH line 39, "injectior" should be --injection-. olumn 10,, line 58, "Light" should .be -Lighter-. Column 12:, line 1, "1" should be --l2--; line 2, "552" should be -'--557-;- claim 5, lines 20, 21 and .22 should be deleted.

Signed and sealed this, 24th day of September 1974.

(SEAL) Attest: I

'McCOY M; GIBSON JR. n I c. MARSHALL DANN' Attesting Officer Comissioner of Patents 

